a.CuCl2 + 2NaOH -> Cu(OH)2 + 2NaCl

     0.15        0.3            0.15            0.3

Cu(OH)2 -> CuO + H2O

  0.15            0.15

nNaOH = 0.3 mol

\(CM_{CuCl2}=\dfrac{0.15}{2}=0.075M\)

b.Vdd sau phản ứng = 0.2 + 0.15 = 0.35l

\(CM_{NaCl}=\dfrac{0.3}{0.35}=0.86M\)

c.mCuO = \(0.15\times80=12g\)

a) \(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)

\(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)

Lập tỉ lệ : \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\)=> Sau phản ứng NaOH dư

\(n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,2\left(mol\right)\)

Dung dịch nước lọc gồm NaCl (0,4_mol); NaOH dư ( 0,1 mol)

\(Cu\left(OH\right)_2-^{t^o}\rightarrow CuO+H_2O\)

\(n_{CuO}=n_{Cu\left(OH\right)_2}=0,2\left(mol\right)\)

\(a=m_{CuO}=0,2.80=16\left(g\right)\)

b) \(m_{NaCl}=0,4.58,5=23,4\left(g\right);m_{NaOH}=0,1.40=4\left(g\right)\)

a/ A+ HCl
CO3 2- + 2H+ ---> H2O+ CO2
dd B trung hòa bởi NaOH--> trong B có Ba(HCO3)2
CO2 + Ba(OH)2 --> BaCO3 + H2O
0.2<---0.25-0.05-------->0.2
2Co2+ Ba(OH)2--> Ba(HCO3)2
0.1<--------0.05<---------0.05
Ba(HCO3)2+ 2NaOH---> BaCO3+ Na2CO3+ 2H2O
0.05<-------------0.1
--> m2= 0.2*197=39,4g
Na2CO3 va K2CO3 : x,y mol

x+y=0.3
138y=106x*2,604
-->x=0.1,y=0.2
--> m1=0.1*106+ 0,2*138=38,2
b/

C%Na2CO3= (0.1*106*100)/ (61,8+ 38,2)=10,6%
C%K2CO3=(0.2*138*100)/(61,8+ 38,2)=27,6%

cái này lấy trên mạng

Sửa đề: 9,2 gam Na

\(a,n_{Na_2O}=\dfrac{9,2}{23}=0,4\left(mol\right)\)

PTHH: \(Na_2O+H_2O\rightarrow2NaOH\)

            0,4------------------>0,8

\(\rightarrow C_{M\left(NaOH\right)}=\dfrac{0,8}{0,5}=1,6M\)

\(b,n_{K_2O}=\dfrac{37,6}{94}=0,4\left(mol\right)\)

PTHH: \(K_2O+H_2O\rightarrow2KOH\)

            0,4----------------->0,8

\(\rightarrow C\%_{KOH}=\dfrac{0,8.56}{362,4+37,6}.100\%=11,2\%\)

a/

\(n_{Na_2O}=\dfrac{9,3}{62}=0,15\left(mol\right)\)

\(Na_2O+H_2O\rightarrow2NaOH\)

0,15 0,3 (mol)

\(m_{NaOH}=0,3.40=12\left(g\right)\)

\(m_A=90,7+9,3=100\left(g\right)\)

\(C\%_{NaOH}=\dfrac{12}{100}.100\%=12\%\)

b/

m\(_{FeSO_4}=\dfrac{16.200}{100}=32\left(g\right)\)

\(\rightarrow m_{FeSO_4}=\dfrac{32}{152}=\dfrac{4}{19}\left(mol\right)\)

\(2NaOH+FeSO_4\rightarrow Na_2SO_4+Fe\left(OH\right)_2\downarrow\)

bđ: 0,3 \(\dfrac{4}{19}\) 0 0 (mol)

pư: 0,3 0,15 0,15 0,15 (mol)

dư: 0 \(\dfrac{23}{380}\) (mol)

\(m_{Fe\left(OH\right)_2}=0,15.90=13,5\left(g\right)\)

\(m_C=100+200-13,5=286,5\left(g\right)\)

\(m_{Na_2SO_4}=0,15.142=21,3\left(g\right)\)

\(\rightarrow C\%_{Na_2SO_4}=\dfrac{21,3}{286,5}.100\%\approx7,4\%\)

\(m_{FeSO_4\left(dư\right)}=\dfrac{23}{380}.152=9,2\left(g\right)\)

\(\rightarrow C\%_{FeSO_4\left(dư\right)}=\dfrac{9,2}{286,5}.100\%\approx3,2\%\)

Đáp án B

a) nBa(OH)2= (200.17,1%)/171=0,2(mol)

nCuSO4=(500.8%)/160=0,25(mol)

PTHH: CuSO4 + Ba(OH)2 -> BaSO4 + Cu(OH)2

+ Kt A có Cu(OH)2 và BaSO4.

+ dd B có dd CuSO4 dư (Vì 0,25/1 > 0,2/1 =>dd CuSO4 dư)

a) mA=mCu(OH)2+ mBaSO4=0,2.98+0,2.233= 66,2(g)

b) mddB= mddBa(OH)2+ mddCuSO4 - mktA= 200+500- 66,2= 633,8(g)

mCuSO4(dư)=(0,25-0,2).160=8(g)

=>C%ddCuSO4(dư)=(8/633,8).100=1,262%

thieu du kien

\(n_{K2O}=\dfrac{9,4}{94}=0,1\left(mol\right)\)

Pt : \(K_2O+H_2O\rightarrow2KOH|\)

         1           1              2

        0,1                        0,2

a) \(n_{KOH}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)

200ml = 0,2l

\(C_{M_{ddKOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\)

b) Pt : \(KOH+HCl\rightarrow KCl+H_2O|\)

              1            1           1            1

            0,1          0,1

\(n_{HCl}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)

\(m_{HCl}=0,1.36,5=3,65\left(g\right)\)

\(m_{ddHCl}=\dfrac{3,65.100}{10}=36,5\left(g\right)\)

c) \(CO_2+2KOH\rightarrow K_2CO_3+H_2O|\)

        1          2               1              1

      0,05      0,1

\(n_{CO2}=\dfrac{0,1.1}{2}=0,05\left(mol\right)\)

\(V_{CO2\left(dktc\right)}=0,05.22,4=1,12\left(l\right)\)

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